Crystal structure and Hirshfeld surface analysis of dichloridotetrakis(4-methyl-1<i>H</i>-pyrazole-κ<i>N</i> <sup>2</sup>)nickel(II) acetonitrile disolvate
نویسندگان
چکیده
The title compound, [NiCl 2 (C 4 H 6 N ) ]·2CH 3 CN, is a mononuclear octahedral Ni II pyrazole-based complex. Two acetonitrile molecules are linked to the complex by N—H...N hydrogen bonds. atom octahedrally coordinated four atoms of 4-methyl-1 -pyrazole ligands, forming equatorial plane. axial positions occupied two Cl atoms. CN was synthesized reaction with nickel(II) chloride hexahydrate in solution under ambient conditions and characterized single-crystal X-ray diffraction analysis. A Hirshfeld surface analysis performed, which suggests that most important contributions contacts from H...H (62.1%), H...N/N...H (13.7%), H...C/C...H (13.4%) H...Cl/Cl...H (10.1%) interactions.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E: Crystallographic Communications
سال: 2022
ISSN: ['2056-9890']
DOI: https://doi.org/10.1107/s2056989022010362